What to Know About Chlorine Dioxide Metal Compatibility 

When it comes to industrial applications, water treatment, and disinfection, chlorine dioxide is a go-to chemical for its potent oxidizing properties. However, one of the critical considerations before implementing a chlorine dioxide system is its compatibility with metals. While oxidizing chemicals can be a powerful agent for sterilization and water purification, they can often be corrosive to certain metals. Chlorine dioxide, however, is quite compatible with the more commonly used metals in these industries. 

Stainless Steel: The Industry Standard 

Stainless steel, particularly the 316L grade, is the most commonly used metal in systems where chlorine dioxide is applied. The reason for its popularity is its excellent resistance to corrosion. Stainless steel forms a passive oxide layer on its surface, which acts as a barrier against corrosive substances like chlorine dioxide. This makes it an ideal choice for water treatment plants, food processing units, and other industrial applications where hygiene and durability are paramount. 

Titanium: The Specialized Choice 

Titanium is another metal that exhibits excellent resistance to chlorine dioxide. While it is generally more expensive than stainless steel, it offers superior corrosion resistance and strength-to-weight ratio. Titanium is often used in specialized applications where extreme conditions, such as high temperatures and pressures, are involved. Its natural resistance to chlorine dioxide makes it a suitable choice for systems that require long-term reliability and minimal maintenance. 

PVC: The Non-Metal Alternative 

Although not a metal, Polyvinyl Chloride (PVC) deserves a mention for its compatibility with chlorine dioxide. PVC is a type of plastic that is often used in piping and storage tanks where chlorine dioxide is used. It is generally less expensive than metal options and offers good chemical resistance. However, it’s essential to note that PVC may not be suitable for high-temperature applications or systems that require high mechanical strength. 

Factors to Consider 


The concentration of chlorine dioxide in the system plays a significant role in determining its compatibility with metals. Higher concentrations are more corrosive and may require specialized materials like titanium for long-term reliability. But for typical applications, concentrations are highly compatible with commonly utilized systems. 


 Temperature is another factor that can accelerate the corrosion process. Metals that are generally compatible with chlorine dioxide at room temperature may start to corrode at elevated temperatures. Therefore, it’s crucial to consider the operating temperature of your system when selecting materials. 

pH Level 

The acidity or alkalinity of the solution can also impact how chlorine dioxide interacts with metals. A balanced pH level can help in maintaining the integrity of the metal components in the system. Chlorine dioxide is effective at a range of pH levels and is known to be a pH neutral biocide. 

Final Thoughts 

Choosing the right materials for your chlorine dioxide system is crucial for its efficiency and longevity. While stainless steel and titanium are excellent choices for most applications, it’s essential to consider factors like concentration, temperature, and pH levels to make an informed decision. Always consult with engineers and experts in the field, and if possible, conduct compatibility tests under your specific conditions. By taking these precautions, you can ensure that your system remains operational for years to come. If you would like to learn more about chlorine dioxide and its compatibility with different metals, please fill out the contact form below, and a PureLine representative will be in contact with you!